题 目：RecentAdvances in 1,2- and 1,4-Azaborine Chemistry
报告人：Prof. Shih-Yuan Liu
Department of Chemistry, Boston College, USA
地 点：19号楼226报告厅
时 间：2018年04月06日（星期五）上午10:00 – 11:00
欢迎听讲!
Abstract
Boron-nitrogen heteroarenes hold great promise for practicalapplication in many areas of chemistry. Enduring interest in realizing thispotential has in turn driven perennial innovation with respect to thesecompounds’ synthesis. This presentation discusses in detail the most recentadvances in methods pertaining to the preparation of BN-isosteres of benzene,naphthalene, and their derivatives. Additional focus is given to the progressenabled by these syntheses toward functional utility of such BN-heterocycles inbiochemistry and pharmacology, materials science, and transition-metal-basedcatalysis.
Figure 1, Synthesis and Applications
Brief Introduction of Prof. Dr. Shih-Yuan Liu
Education
2003-2006 MassachusettsInstitute of Technology, Postdoctoral. Advisor: Daniel G. Nocera
1998-2003 MassachusettsInstitute of Technology, Ph. D. (2003). Advisor: Gregory C. Fu
1997-1998 University of NorthCarolina, Chapel Hill. Undergraduate Exchange Student
1995-1997 Vienna University ofTechnology, 1st Diploma in Chemistry (B.S. equivalent, 1998)
ProfessionalAppointments
2013- Full Professor of Chemistry, Boston College
2012-2013 Associate Professorof Chemistry, University of Oregon
2013-2016 Assistant Professorof Chemistry, University of Oregon
Awards
2016 FriedrichWilhelm Bessel Research Award of the Alexander von Humboldt Foundation
2014 ACSOrganometallics Young Investigator Fellow
2012 CamilleDreyfus Teacher-Scholar Award
2012 Journal ofPhysics Organic Chemistry Award for Early Excellence
SelectedPublications:
(1)“AHybrid Organic/Inorganic Benzene” Marwitz, A. J. V.; Matus, M. H.; Zakharov, L.N.; Dixon, D. A.; Liu, S.-Y. Angew. Chem. Int. Ed.2009, 48,973-977.
(2) “Boron in Disguise: The Parent"Fused" BN Indole” Abbey, E. R.; Zakharov, L. N.; Liu, S.-Y. J.Am. Chem. Soc. 2011, 133, 11508-11511.
(3) “1,2-BN Cyclohexane: Synthesis,Structure, Dynamics, and Reactivity” Luo, W.; Zakharov, L. N.; Liu, S.-Y. J.Am. Chem. Soc.2011, 133, 13006-13009..
(4) “A1,3-Dihydro-1,3-azaborine Debuts” Xu, S.; Zakharov, L. N.; Liu, S.-Y. J. Am.Chem. Soc.2011, 133, 20152-20155.
(5) “Two BNIsosteres of Anthracene: Synthesis and Characterization” Ishibashi, J. S. A.;Marshall, J. L.; Maziere, A.; Lovinger, G. J.; Li, B.; Zakharov, L. N.;Dargelos, A.; Graciaa, A.; Chrostowska, A.; Liu, S.-Y. J. Am. Chem. Soc.2014, 136, 15414-15421.
(6) "The State of the Art in AzaborineChemistry: New Synthetic Methods and Applications" Giustra, Z. X.; Liu,S.-Y. J. Am. Chem. Soc.2018, 140,1184-1194.
